Petroleum (L. petroleum, from Greek πετρέλαιον, lit.
"rock oil") or crude oil is a naturally occurring, flammable
liquid found in rock formations in the Earth consisting of a
complex mixture of hydrocarbons of various molecular weights,
plus other organic compounds.
The term "petroleum" was first used in the treatise De Natura
Fossilium, published in 1546 by the German mineralogist Georg
Bauer, also known as Georgius Agricola.
Petroleum is basically a mix of naturally occurring organic
compounds from within the earth that contain primarily
hydrogen, carbon and oxygen. When petroleum comes straight
out of the ground as a liquid it is called crude oil if dark
and viscous, and condensate if clear and volatile. When solid
it is asphalt, and when semi-solid it is tar. There is also
natural gas, which can be associated with oil or found
alone.
Crude oil comes in many forms. Usually it is black, but green,
red or brown oils are not uncommon. Thin and volatile oils are
called "light", whereas thick and viscous ones are "heavy". Light
oils have an API gravity of 30 to 40 degrees, which means that
the density is much less than 1.0 g/cc. These oils float easily
on water. By contrast, some heavy oils have an API gravity of
less than 12 degrees and are so dense that they sink, rather than
float, in water.
Most oils are mixtures of many different compounds, most
of which are hydrocarbons. There are four main hydrocarbon
groups in petroleum. The saturates are hydrocarbons consisting
of straight chains of carbon atoms. Aromatics are hydrocarbons
consisting of rings of carbon. Asphlatenes are complex
polycylic hydrocarbons that contain many complicated carbon
rings, and NSO compounds are mostly nitrogen, sulfur, and
oxygen.
In most oils, the saturate fraction is the largest and is made
up of two subgroups called paraffins and isoprenoids. Paraffins
are simple straight-chain hydrocarbons, whereas isoprenoids are
hydrocarbon chains with branches. Waxes are long-chain
paraffins that are solid at surface temperatures and may
contain as many as 50 carbon atoms. Waxy oils tend to thick and
viscous, whereas aromatic oils tend to be light and
volatile.
Petroleum in ancient times was called bitumen, and mankind
for centuries was not at all sure what bitumen was made of or
where it came from. Two ideas developed in ancient times to
explain the composition and origin of bitumen. One held that
bitumen was inorganic and bore no relation to living things,
whereas the other theorized that it somehow formed from
once-living plants or animals.
Plato and Aristotle discussing philosophyThe ancient Greek
philosopher Aristotle taught that everything we touch or feel is
made up of the base elements of earth, air, fire and water. These
elements are never found in a pure state and consist of a
mysterious matrix infused with the properties of warm and dry, or
the opposing properties of cold and wet. Earth was dry and cold,
air wet and hot, fire dry and hot, and water wet and cold.
Aristotle believed that stones, ores and fossils form as
deposits from exhalations deep within the earth that are trapped
in pores and fissures. Wet exhalations produce metals, dry ones
produce stones. Aristotle's followers suggested that the foul
smell associated with most bitumen indicated that it was a form
of liquid sulfur, a compound they attributed to dry
exhalations.
Two theories on the origin of petroleum developed during the
Renaissance. The more popular was proposed by Agricola, a German
physician who agreed with Aristotle and wrote in 1546, in a
textbook on mining and minerals, that bitumen formed from
exhalations of sulfur deep within the earth. By contrast,
Libavius, another German physician, theorized in 1599, in a
chemistry textbook, that bitumen might form from the resins of
ancient trees.
Leo Lesqueroux, the father of paleobotany, decided in
1866 that petroleum in Pennsylvania formed from marine algae in
Devonian shales much the same way that coal forms from land
plants. Later, Anderson and Arnold convincingly argued in a
1907 bulletin of the U.S. Geological Survey that the only
possible source for oils from Santa Maria field in California
was microscopic fossil plants, called diatoms, found in
organic-rich shales of the Miocene Monterey Formation. Another
bulletin by Clarke in 1916 demonstrated that the Santa Maria
oils were chemically similar to, and therefore undoubtedly
derived from, the organic remains of Monterey diatoms.